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Open AMPPS Control Panel
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Click on home button on AMPPS panel Or visit http://localhost/ampps/
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On AMPPS home page click on 'add domain' under Features section.
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On Add Domain page fill domain name and related information as per your need.
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To issue self signed certificate for your site check the checkbox infront of Add an SSL entry (as shown in screenshot below)
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Then Click on Add Domain button.
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After this sll entry will be added for your domain in httpd-vhost.conf. You can find certificates at \path\to\Ampps\apache\conf\ssl_crt folder